Experimental and Computational Study of Co(II), Ni(II) and Zn(II) Complexes with the Azo Dye Derived from 2-Amino-4-Methyl Pyridine and β-Naphtol
Experimental and Computational Study of Co(II), Ni(II) and Zn(II) Complexes with the Azo Dye Derived from 2-Amino-4-Methyl Pyridine and β-Naphtol

Summary/Abstract: A series of metal complexes of Co(II), Ni(II), Cu(II) and Zn(II) complexes with the azodye ligand derived from the 4-methyl-2-aminopyridine and β-napthol have been synthesised. These complexes and the ligand have been characterised by analytical and spectral techniques such as IR, NMR, electronic and magnetic measurement. The structural compositions of the ligand and complexes have been determined by FAB-MS structural studies. The computational study of studied compounds has been made to determine geometrical parameters and electronic parameters. The experimental data of the compounds are compared with the computationally generated data. The structural activity relationships of all the compounds have been computed to explain their biological properties.

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